What Factors Influence the Internal Temperature of Polyurethane Soft Foam?

PU foam

The internal temperature of foam is essential for determining its physical properties. If the post-curing temperature of the foam is too low, the foam’s properties will not be optimal and may fluctuate significantly.

Once the foam is fully formed, the internal temperature can rise rapidly to over 120°C due to the exothermic reaction and poor heat dissipation, posing a fire hazard.

The internal temperature is crucial for ensuring the foam’s superior properties. Foam cured at specific external temperatures exhibits excellent properties, such as high tensile strength. Some calculate the internal temperature using formulas, while others use software to automate this calculation. What factors, then, influence the internal temperature? Is understanding these factors important? Just as modern smartphones have high-resolution cameras but professional photography still requires control over aperture, focal length, and exposure, controlling the foam’s internal temperature requires understanding its key variables.

Basic Principles

1.Heat Distribution and Space: The temperature of a space is proportional to the amount of heat injected and inversely proportional to the space’s volume. For example, distributing 10 kJ of heat in an 8-liter space results in a temperature of 20°C, while in a 4-liter space, the temperature rises to 40°C.

2.Heat Input Rate: The amount of heat input depends on the value of the heat and the rate at which it is introduced. For instance, releasing 100 kJ of heat at a speed of “v” results in an input of “A,” while releasing it at 2v results in an input of 2A.

3.Volume and Absolute Temperature: The volume of a space increases with absolute temperature. For example, a 1-liter space at 0°C expands to 1.366 liters at 100°C.

4.Volume and Atmospheric Pressure: The volume of a space is inversely proportional to atmospheric pressure.

5.Methane Vaporization: The delay in methane vaporization must be considered, as it affects heat absorption.

Impact of Formula Adjustments

Fine-tuning the formula can affect the internal temperature of the foam. For example, increasing methane by 5% reduces the internal temperature because methane absorbs heat during vaporization, lowering the heat input and increasing the space to accommodate the heat. Conversely, increasing the water content by 5% increases the internal temperature because the water releases heat and the reaction generates gas, expanding the space. In this case, the increased heat input outweighs the cooling effect of the gas expansion.

In scenarios where changes in foam index, heat release, and dissipation occur simultaneously, it becomes challenging to predict the internal temperature change without precise calculations or measurements. This requires using formulas derived from the basic principles, such as the heat released when water reacts with TDI to form carbon dioxide and the heat absorbed during methane vaporization.

Understanding these factors is crucial for accurately predicting and controlling the internal temperature, ensuring optimal foam properties.

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